Tecnoflon® PFR FFKM perfluoroelastomers show the ultimate performance among all elastomers. They are resistant to nearly every chemical class with some grades offering heat resistance over 300°C, making Tecnoflon® PFR the material of choice for high demanding sealing applications. Market specific grades have been specially developed to answer the stringent requirements of the semiconductor, oil & gas and chemical processing industries.

Tecnoflon® PFR FFKM cover the widest temperature range among all elastomers.

Elastomer Service Temperatures


Tecnoflon® PFR FFKM show the best-in-class chemical resistance among all elastomers, and will only be affected by fluorinated fluids.

Chemical resistance

Inorganic acids C C C B A A
Organic acids B B D C C A
Alkalis B B B B A A
Amines A A D D A A
Steam C B C C A A
Ketones D C D D D A
Esters D B D D D A
Ethers A A A D D A
Aldehydes D B D D D A
Alcohols A A A B A A
Aliphatic Hydrocarbons A D A A B A
Aromatic Hydrocarbons D D C A D A
Sour gas C C C B A A
Lubricants A A A A A A
Fluorinated fluids A D C D D C

A = <10% volume swelling 
B = 10-30% volume swelling 
C = 30-50% volume swelling 
D = >50% volume swelling

Tecnoflon® PFR FFKM Grades

Chemical Resistant Grades

Tecnoflon® PFR 94 & Tecnoflon® PFR 06HC

Tecnoflon® PFR 94 and PFR 06HC have been specially designed for the Chemical Process and Oil & Gas industries, delivering the highest chemical resistance among all elastomers; specifically they outperform FKMs when in contact with polar fluids (such as ketones, esters, ethers and aldehydes) and bases (alkalis and amines).

Chemical Resistance in Ketones



Chemical Resistance in Amines



High Temperature Resistant Grades

Tecnoflon® PFR 95 & Tecnoflon® PFR 95HT

With Solvay’s proprietary cross-linking technology, Tecnoflon® PFR 95 and PFR 95HT provide superior thermal resistance versus general purpose FFKM, maintaining their sealing properties at high temperatures and outperforming other high temperature cross-linking technologies under steam at high temperatures.

Compression Set Variation at High Temperatures



Steam Resistance



High Purity Grades

Tecnoflon® PFR 5910M & Tecnoflon® PFR 5920M

Tecnoflon® PFR 5910M and PFR 5920M have been specially designed for the semiconductor industry to eliminate the use of mineral fillers, avoiding particle generation in the chambers using aggressive plasma conditions. Solvay’s co-coagulation proprietary technology allows the introduction of PTFE particles smaller than 40nm and ensures an excellent dispersion of those particles, resulting in equivalent mechanical properties to mineral filled perfluoroelastomers and better than other organic filled materials available in this market.

Low Particle Generation

Zero residual mass after TGA in nitrogen indicates that the material is fully organic, greatly reducing the chances of generating particles in the plasma chambers.

TGA in Nitrogen Comparison


Comparison of Organic Filled FFKMs – SEM Images

Solvay Proprietary Technology



Extrusion Blending Technology



Open Mill Mixing Technology



With Solvay co-coagulation proprietary technology, PTFE particles are observable with far greater difficulty, even by SEM, thanks to excellent sub-micron size dispersion. This technology achieves mechanical properties equivalent to those of mineral-filled perfluoroelastomer compounds.

Typical Metal Content

Solvay technology allows to obtain the the highest purity among commercial sealing solutions in the semicon market

Bulk Ash Analysis



Tecnoflon® PFR 5910M: Solvay Technology 
FFKM 1: Amber translucent organic filled FFKM 
FFKM 2: Black FFKM for semiconductor wet processing 
FKM 1: High-performance FKM for plasma dry processes


Mechanical Properties Comparison

The excellent PTFE dispersion at the nanoscale allows to attain physical properties which are similar to conventional mineral filled compounds and better than traditional PTFE powder mixing.

Tensile Strength Comparison



Compression Set Comparison



Low Temperature Resistant Grades

Tecnoflon® PFR LT is specially developed to match the latest and most stringent requirements of the Oil & Gas industry.

Solvay's proprietary MOVE technology delivers a perfluoroelastomer with outstanding chemical resistance and unrivaled extended low temperature flexibility with TR10=-30°C.

Minimum Service Temperature



Rapid Gas Decompression (RGD) occurs when external gas pressure rapidly reduces in operation; this may result in splitting, internal cracking and blistering of the seals.

Thanks to Solvay’s proprietary Branching and Pseudo-living technology, Tecnoflon® PFR possess excellent properties to withstand Rapid Gas Decompression.

Tecnoflon® PFR LT, along with most Tecnoflon® PFR FFKM, has been tested according the Industry recognized NORSOK Standard M-710 Rev 2, and successfully passed the RGD test.



RGD test conditions 

Gas: 90/10 mol% CH4/CO2 
O-rings per material: 6 
Groove fill, %: 65 and 80 
Temperature: 100°C 
Pressure: 150 bar 
No. of cycles: 10 
First cycle duration: 72 hours 
Cycles 2-10, duration: 23-24 hours 
Hold period between cycles: 1 hour 
De-pressurization rate: 20 bar/minute 
Sampling after cycles: 10

NORSOK M-710, “Qualification of non-metallic sealing materials and manufacturers”, Rev 2, October 2001


Processing Recommendations

All Tecnoflon® PFR are peroxide curable materials; thanks to Solvay Specialty Polymers proprietary polymerization technology, this translates into very easy process ability, from compound mixing, to preforming, molding and post-curing.

  • Easy compounding with two-roll mills; no exotic chemicals are needed
  • Very simple preforming, preferably by screw extruders
  • Short curing cycles at relatively low temperatures (from 150 to 180°C)
  • Relatively short post-curing cycles in air circulating oven (max 24 h)

Tecnoflon® PFR behave similarly to peroxide cured fluoroelastomers, in terms of ingredients used for compounding, processing conditions as well as shrinking rates. This means that standard process equipment (open mills, presses, tools and ovens) for FKMs is suitable to Tecnoflon® PFR seals manufacturing too.


Tecnoflon® PFR perfluoroelastomers are best suited for two-roll mills mixing. The elastomer must be at first pre-heated by loading it onto the open mill with a wide enough gap between the rollers and progressively reducing the gap. Once the rubber has covered most of the roller width, sticking on the fast cylinder, the ingredients, previously mixed, are progressively added, taking care to distribute them along the whole length of the rollers.

After the incorporation and the preliminary dispersion of the ingredients, the compound is completed by working with a reduced gap aiming at dispersing completely and homogenizing the ingredients. In this phase, the technician operates 6 cuts of the compound in diagonal up to ¾ of the length of the cylinder, alternatively from the left to right and vice versa. After that, the compound is discharged.

Tecnoflon® PFR compounds can be readily processed by means of conventional elastomer processing methods such as compression, transfer and injection molding. Alternatively they can be extruded into hoses or profiles and subsequently cured in an autoclave.

Preforming (by extrusion)

When processing Tecnoflon® PFR by means of compression molding into seals, pre-forming (i.e. the shaping of the uncured compound in the form of a cord) is recommended. This optimizes the manufacturing process as well as enhances the seal performance. Additionally accurate compound pre-forming reduces the amount of flash, resulting in less process waste and improved efficiency. It is recommended to carry out the pre-forming by means of conventional elastomer screw extruders with L/D ratio falling in the range between 6 and 12. Ram extruders can be used for the same purpose but, due to their different layout, they’re less efficient than screw extruders in keeping a smooth and constant size extrudate.

Extrusion parameters must be fine tuned according to the compound properties and the apparatus design; as starting point, 50°C for the barrel and 70°C for the die are recommended. The operating conditions, when set properly, will results in a smooth and constant profile. Particular care must be taken to prevent excessive heat buildup in the compound which will result in scorching.


Vulcanization of the compounds is most commonly carried out in compression moulding presses. The process conditions depend on the compound, the press and the tool design as well as on the item geometry. However PFR 94 and PFR 06HC based compounds can be effectively moulded at 160°C, while 175 °C is the optimal curing temperature for PFR 95, PFR 95HT, PFR 5910M and PFR 5920M compounds. The curing time depends mainly on the items size and geometry, for instance the larger the cross-section, the longer the curing time.

Post Cure

Post cure step is needed for all FFKMs in order to complete the cure, eliminate impurities and strengthen filler-polymer interactions. Post cure parameters are related to the oven type. Therefore optimal conditions must be tuned to the system in use. As starting point for the optimization, the following are recommended when ovens with 7 to 14 complete air changes per hour are used:

  • PFR 94 and PFR 06HC: 4 h @ 230°C
  • PFR 95 and white PFR 95HT: 8 hours rise from RT to 250°C followed by 16 hours at 250°C
  • Black PFR 95HT: 8 hours rise from RT to 290°C followed by 16 hours at 290°C
  • Translucent PFR 5910M and PFR 5920M: 8 h @ 230°C

For higher number of air changes (i.e. > 50 per hour), milder conditions (i.e. lower temperatures and/or shorter times) are advisable.